# Basic process of radiometric dating

### NPTEL :: Physics - Nuclear Science & Engineering

Basic Formulation on Radioactive Dating process. Determination of age of any geological or archeological object is an extremely important task to know the. Basic Principles of Radiometric Dating. Radiometric dating is based on a process in which various elements emit atomic particles. This breakdown process is. Radiometric dating is often used to “prove” rocks are millions of So let's take a closer look and see how reliable this dating method really is.

It is not affected by external factors such as temperaturepressurechemical environment, or presence of a magnetic or electric field. For all other nuclides, the proportion of the original nuclide to its decay products changes in a predictable way as the original nuclide decays over time.

This predictability allows the relative abundances of related nuclides to be used as a clock to measure the time from the incorporation of the original nuclides into a material to the present. Accuracy of radiometric dating[ edit ] Thermal ionization mass spectrometer used in radiometric dating. The basic equation of radiometric dating requires that neither the parent nuclide nor the daughter product can enter or leave the material after its formation.

The possible confounding effects of contamination of parent and daughter isotopes have to be considered, as do the effects of any loss or gain of such isotopes since the sample was created. It is therefore essential to have as much information as possible about the material being dated and to check for possible signs of alteration. Alternatively, if several different minerals can be dated from the same sample and are assumed to be formed by the same event and were in equilibrium with the reservoir when they formed, they should form an isochron.

This can reduce the problem of contamination. In uranium—lead datingthe concordia diagram is used which also decreases the problem of nuclide loss.

Finally, correlation between different isotopic dating methods may be required to confirm the age of a sample.

For example, the age of the Amitsoq gneisses from western Greenland was determined to be 3. The procedures used to isolate and analyze the parent and daughter nuclides must be precise and accurate.

This normally involves isotope-ratio mass spectrometry. For instance, carbon has a half-life of 5, years. After an organism has been dead for 60, years, so little carbon is left that accurate dating cannot be established. On the other hand, the concentration of carbon falls off so steeply that the age of relatively young remains can be determined precisely to within a few decades. Closure temperature If a material that selectively rejects the daughter nuclide is heated, any daughter nuclides that have been accumulated over time will be lost through diffusionsetting the isotopic "clock" to zero.

The temperature at which this happens is known as the closure temperature or blocking temperature and is specific to a particular material and isotopic system.

These temperatures are experimentally determined in the lab by artificially resetting sample minerals using a high-temperature furnace. As the mineral cools, the crystal structure begins to form and diffusion of isotopes is less easy. At a certain temperature, the crystal structure has formed sufficiently to prevent diffusion of isotopes. This temperature is what is known as closure temperature and represents the temperature below which the mineral is a closed system to isotopes.

Thus an igneous or metamorphic rock or melt, which is slowly cooling, does not begin to exhibit measurable radioactive decay until it cools below the closure temperature. The age that can be calculated by radiometric dating is thus the time at which the rock or mineral cooled to closure temperature.

This field is known as thermochronology or thermochronometry. The age is calculated from the slope of the isochron line and the original composition from the intercept of the isochron with the y-axis.

The equation is most conveniently expressed in terms of the measured quantity N t rather than the constant initial value No. The above equation makes use of information on the composition of parent and daughter isotopes at the time the material being tested cooled below its closure temperature. This is well-established for most isotopic systems.

Plotting an isochron is used to solve the age equation graphically and calculate the age of the sample and the original composition. Modern dating methods[ edit ] Radiometric dating has been carried out since when it was invented by Ernest Rutherford as a method by which one might determine the age of the Earth.

In the century since then the techniques have been greatly improved and expanded.

## How Does Carbon Dating Work

The mass spectrometer was invented in the s and began to be used in radiometric dating in the s. It operates by generating a beam of ionized atoms from the sample under test.

The ions then travel through a magnetic field, which diverts them into different sampling sensors, known as " Faraday cups ", depending on their mass and level of ionization. On impact in the cups, the ions set up a very weak current that can be measured to determine the rate of impacts and the relative concentrations of different atoms in the beams. Uranium—lead dating method[ edit ] Main article: Uranium—lead dating A concordia diagram as used in uranium—lead datingwith data from the Pfunze BeltZimbabwe.

This scheme has been refined to the point that the error margin in dates of rocks can be as low as less than two million years in two-and-a-half billion years. Zircon has a very high closure temperature, is resistant to mechanical weathering and is very chemically inert.

Zircon also forms multiple crystal layers during metamorphic events, which each may record an isotopic age of the event. This can be seen in the concordia diagram, where the samples plot along an errorchron straight line which intersects the concordia curve at the age of the sample. Samarium—neodymium dating method[ edit ] Main article: Samarium—neodymium dating This involves the alpha decay of Sm to Nd with a half-life of 1. Accuracy levels of within twenty million years in ages of two-and-a-half billion years are achievable.

Potassium—argon dating This involves electron capture or positron decay of potassium to argon Potassium has a half-life of 1. Rubidium—strontium dating method[ edit ] Main article: Rubidium—strontium dating This is based on the beta decay of rubidium to strontiumwith a half-life of 50 billion years. This scheme is used to date old igneous and metamorphic rocksand has also been used to date lunar samples. Closure temperatures are so high that they are not a concern.

Rubidium-strontium dating is not as precise as the uranium-lead method, with errors of 30 to 50 million years for a 3-billion-year-old sample.

Uranium—thorium dating method[ edit ] Main article: Beta particles are products of radiocarbon decay. In this method, the carbon sample is first converted to carbon dioxide gas before measurement in gas proportional counters takes place. Liquid scintillation counting is another radiocarbon dating technique that was popular in the s.

In this method, the sample is in liquid form and a scintillator is added. This scintillator produces a flash of light when it interacts with a beta particle. A vial with a sample is passed between two photomultipliers, and only when both devices register the flash of light that a count is made. Accelerator mass spectrometry AMS is a modern radiocarbon dating method that is considered to be the more efficient way to measure radiocarbon content of a sample.

In this method, the carbon 14 content is directly measured relative to the carbon 12 and carbon 13 present. The method does not count beta particles but the number of carbon atoms present in the sample and the proportion of the isotopes. Carbon Datable Materials Not all materials can be radiocarbon dated.

## Radiometric dating

Most, if not all, organic compounds can be dated. Samples that have been radiocarbon dated since the inception of the method include charcoalwoodtwigs, seedsbonesshellsleather, peatlake mud, soilhair, potterypollenwall paintings, corals, blood residues, fabricspaper or parchment, resins, and wateramong others. Physical and chemical pretreatments are done on these materials to remove possible contaminants before they are analyzed for their radiocarbon content.

Carbon Dating Standards The radiocarbon age of a certain sample of unknown age can be determined by measuring its carbon 14 content and comparing the result to the carbon 14 activity in modern and background samples.

### Radiometric dating - Wikipedia

The principal modern standard used by radiocarbon dating labs was the Oxalic Acid I obtained from the National Institute of Standards and Technology in Maryland. This oxalic acid came from sugar beets in When the stocks of Oxalic Acid I were almost fully consumed, another standard was made from a crop of French beet molasses.

Over the years, other secondary radiocarbon standards have been made. Radiocarbon activity of materials in the background is also determined to remove its contribution from results obtained during a sample analysis.

Background samples analyzed are usually geological in origin of infinite age such as coal, lignite, and limestone. The CRA conventions include a usage of the Libby half-life, b usage of Oxalic Acid I or II or any appropriate secondary standard as the modern radiocarbon standard, c correction for sample isotopic fractionation to a normalized or base value of These values have been derived through statistical means. Radiocarbon Dating Pioneer American physical chemist Willard Libby led a team of scientists in the post World War II era to develop a method that measures radiocarbon activity.

He is credited to be the first scientist to suggest that the unstable carbon isotope called radiocarbon or carbon 14 might exist in living matter.